Glutamine - an amino acid. Your body makes it from protein. During exercise or stress your muscles can become severely depleted. Recommended use, first thing in the morning and/or right before exercise. Comes in capsules or powders. IMHO, never felt like it did much and kind of expensive. I feel that if I'm getting enough protein, I'm covered.
Water - I recommend drinking 8-10 glasses spread over the day. Too much at one time makes me feel bloated and just rushes to the bathroom.
Creatine - One of the big three for gains, they're a multivitamin, protein and creatine. Best taken after your workout with a small to moderate simple carb and protein "recovery" shake.
Protein - recommend 1-2 grams per pound of bodyweight.
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