That depends, but the answer is probably 'no' for the most part and "yes" for B2

The key point is that the RDA is not considered a dose that would help you if you were feeling bad or if you had deficiencies. For example, the RDA for vitamin C is so low that about the only thing it does is keep you from getting scurvey, it doesn't really benefit you.
Being female and having symptoms of PMS you would probably feel better with a little more of the B's, some magnesium (w/ calcium) and some healthy fats (Omega complex from either food or supplements). Good sources of EFAs are Fatty fish, linseed oil (flax oil and seeds), hemp oil, evening oil of primrose, and walnuts. You can often find a supplement aimed directly at PMS symptoms which will contain many of these (Evening Oil of Primrose, Black Cohosh, Omega 3&G and Hemp are all sold as supplements); or you can start putting a few new things into your diet (or increasing them if you already do eat them)
Vit B12 in particular can help with mood and cognitive function - I'm sure you've heard of B12 injections? These typically contain levels as high as 3000mcg. I'm not suggesting this much, by any means, but 3mcg really isn't going to alleviate anything.
Your levels of B2 and B6 seem fine (we do tend to get these from our diets and deficiencies aren't usually an issue), are you taking them individually? It might be more effective (both in terms of time and money) to get a B complex which contains all the Bs along with some Folic Acid (folate).
Nat